Title of article
Synthetic, spectroscopic and structural studies of two novel phosphanyl(organyl)borane compounds
Author/Authors
Sonia G. Thangavelu، نويسنده , , Kathryn E. Hocker، نويسنده , , Shayna R. Cooke، نويسنده , , Clare N. Muhoro، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
5
From page
562
To page
566
Abstract
The titanium (II) complex, Cp2Ti(HBcat)2, catalyzes the hydroboration of diphenylvinylphosphine by catecholborane and pinacolborane to afford exclusive anti-Markovnikov phosphanyl(organyl)boranes cleanly, rapidly and in good yields. Spectroscopic and X-ray studies of the phosphanyl(organyl)borane products show no evidence of boron–phosphorus interaction, indicating that the compounds preclude formation of Lewis pairs.
Keywords
Phosphanyl(organyl)boranes , Catecholborane , Vinylphosphines , pinacolborane , Titanium-catalyzed hydroboration
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376296
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