Title of article
Phenylsilanetriol — synthesis, stability, and reactivity
Author/Authors
S.D Korkin، نويسنده , , M.I Buzin، نويسنده , , E.V Matukhina، نويسنده , , L.N Zherlitsyna، نويسنده , , N Auner، نويسنده , , O.I Shchegolikhina، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
8
From page
313
To page
320
Abstract
Crystalline phenylsilanetriol, PhSi(OH)3 (1) was obtained by smooth hydrolysis of phenyltrimethoxysilane and characterised by different analytical methods (wide angle X-ray powder diffraction, NMR, IR, thermogravimetric analysis). The title-compound is surprisingly stable in the solid state but slowly condenses in acetone solution. Reaction of 1 with Me3SiCl and Me2(CH2Cl)SiCl gave the corresponding tris-triorganylsiloxy substituted derivatives in high yields.
Keywords
Trimethylsilylation , Phenylsilanetriol , Stability , Wide angle X-ray powder diffraction (WAX) , TGA , NMR- and IR-spectroscopy
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376459
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