Title of article :
A new platinum vapor-derived highly efficient hydrosilylation catalyst: NMR structural investigation
Author/Authors :
Gloria Uccello Barretta، نويسنده , , Federica Balzano، نويسنده , , Claudio Evangelisti، نويسنده , , Patrizio Raffa، نويسنده , , Alessandro Mandoli، نويسنده , , Samuele Nazzi، نويسنده , , Giovanni Vitulli، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2008
Abstract :
The structural features of a highly efficient hydrosilylation catalyst generated by reaction of Pt vapor and a mixture of mesitylene and 1,3-divinyltetramethyldisiloxane (DVS) were investigated by mono- and bidimensional NMR analyses. The structure around the Pt atoms was highlighted and compared with a commercial sample (Karstedt catalyst) and previously reported Pt vapor-derived system.
Keywords :
NMR , DOSY , Platinum , Hydrosilylation
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
