Title of article
Palladium-catalyzed novel addition–elimination reaction of alkenyltin reagents to norbornene
Author/Authors
Keigo Fugami، نويسنده , , Yasuyuki Hirunuma، نويسنده , , Takashi Nishikata، نويسنده , , Daisuke Koyama، نويسنده , , Masayuki Kameyama، نويسنده , , Masanori Kosugi، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
3
From page
567
To page
569
Abstract
Palladium-catalyzed reaction between 1-alkenyltin trichlorides and norbornene resulted in stereoselective formation of 3-alkylidenepentacyclo[9.2.1.5,81.1,110.2,1004,9]pentadecane instead of an expected simple alkenylstannylation product. Generation of trichlorostannane and its decomposition product, tin(II) chloride, was confirmed by trapping it with methyl propiolate and norbornene and analysis of the reaction by 119Sn NMR, respectively.
Keywords
Heck reaction , Palladium-catalyst , Organotin reagent , Halide , addition–elimination
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376564
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