Title of article :
Reactivity of di-n-butyl-dicyclopentadienylzirconium towards amido stabilized stannylenes
Author/Authors :
Josef Bare?، نويسنده , , Zde?ka Pad?lkov?، نويسنده , , Philippe Meunier، نويسنده , , Nadine Pirio، نويسنده , , Ale? R??i?ka، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2009
Abstract :
Reaction of Sn[(N(C6H3iPr2-2,6)(SiMe3)]2 and [{Sn(N(C6H3iPr2-2,6)(SiMe3)(μ-Cl)2] with di-n-butyl-dicyclopentadienylzirconium yielded the trimetallic a carbene-like complex {[(N(C6H3iPr2-2,6)(SiMe3)](n-Bu)Sn}2Cp2Zr. The oxidation of {[(N(C6H3iPr2-2,6)(SiMe3)](n-Bu)Sn}2Cp2Zr by oxygen gives the five-membered dioxadistannazirconacyclic complex {[(N(C6H3iPr2-2,6)(SiMe3)](n-Bu)Sn}2O2Cp2Zr.
Keywords :
Oxidation , zirconocene , Stannylene , NMR
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
