Title of article :
Tris(trimethylsilylmethyl)alane: an aldehyde selective peterson methylenation reagent
Author/Authors :
Vahak Abedi، نويسنده , , Merle A. Battiste، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2004
Abstract :
Tris(trimethylsilylmethyl)alane (TTMA) is a rapid, efficient, and highly aldehyde-selective trimethylsilylmethylating reagent. A solid lithium halide complex of the reagent, TTMA · 3LiBr (TTMAs), is particularly effective in this transformation to the Peterson alcohol intermediate.
Keywords :
Aldehyde vs. ketone selectivity , Peterson methylenation , Tris(trimethylsilylmethyl)alane
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
