• Title of article

    Investigation of Hg(SiMe3)2 and Me3Si radical by photoelectron spectroscopy and theoretical methods

  • Author/Authors

    Benedek Imre K?rolyi، نويسنده , , L?szl? Szepes، نويسنده , , G?bor Vass، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2010
  • Pages
    3
  • From page
    1609
  • To page
    1611
  • Abstract
    He I photoelectron spectra of bis-(trimethylsilyl)-mercury and its gas phase thermolysis product, Me3Si radical, are reported. The first vertical ionization energies were determined to be 7.37 and 7.32 eV, respectively, and compared to calculated values as obtained at different levels of theory. The interpretation of spectra together with the nature of Si-Hg-Si bond is discussed.
  • Keywords
    He I photoelectron spectroscopy , Thermolysis , Ionization energy , Theoretical calculations , bis-(Trimethylsilyl)-mercury , Trimethylsilyl radical
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2010
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1377132