Title of article
Investigation of Hg(SiMe3)2 and Me3Si radical by photoelectron spectroscopy and theoretical methods
Author/Authors
Benedek Imre K?rolyi، نويسنده , , L?szl? Szepes، نويسنده , , G?bor Vass، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2010
Pages
3
From page
1609
To page
1611
Abstract
He I photoelectron spectra of bis-(trimethylsilyl)-mercury and its gas phase thermolysis product, Me3Si radical, are reported. The first vertical ionization energies were determined to be 7.37 and 7.32 eV, respectively, and compared to calculated values as obtained at different levels of theory. The interpretation of spectra together with the nature of Si-Hg-Si bond is discussed.
Keywords
He I photoelectron spectroscopy , Thermolysis , Ionization energy , Theoretical calculations , bis-(Trimethylsilyl)-mercury , Trimethylsilyl radical
Journal title
Journal of Organometallic Chemistry
Serial Year
2010
Journal title
Journal of Organometallic Chemistry
Record number
1377132
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