Title of article
Hydrostannation of norbornadiene by nBu3SnH and Ph3SnH with molybdenum catalysts
Author/Authors
Magdalena Zyder، نويسنده , , Teresa Szyma?ska-Buzar، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2010
Pages
4
From page
1734
To page
1737
Abstract
Photochemically activated [Mo(CO)6] and [Mo(CO)4(η4-nbd)] are demonstrated to be good catalysts for the hydrostannation of norbornadiene (nbd) by stannyl hydrides (nBu3SnH and Ph3SnH) to give stannylnorbornene in ca. 100% yield. The reaction was carried out at room temperature in n-heptane (20 cm3) with continued photolysis (2 h) at Mo(CO)6: R3SnH:nbd = 1:50:50.
Keywords
Stannylnorbornene , hydrostannation , Norbornadiene , Molybdenum catalyst , Photolysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2010
Journal title
Journal of Organometallic Chemistry
Record number
1377166
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