Title of article
Synthesis and characterization of a dinuclear platinum complex with silsesquioxanate ligand
Author/Authors
Neli Mintcheva، نويسنده , , Makoto Tanabe، نويسنده , , Kohtaro Osakada، نويسنده , , Ivelina Georgieva، نويسنده , , Tzvetan Mihailov، نويسنده , , Natasha Trendafilova، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2010
Pages
6
From page
1738
To page
1743
Abstract
The first dinuclear platinum complex with a silsesquioxanate ligand {[Pt(Ph)(PEt3)2]2O11Si7(c-C5H9)7(OH)} was synthesized by reaction of incompletely condensed silsesquioxane, (c-C5H9)7Si7O9(OH)3 with trans-PtI(Ph)(PEt3)2. Multinuclear (1H, 13C, 29Si, and 31P) NMR data clearly show two unequivalent platinum moieties (Pt(Ph)(PEt3)2) bridged by bulky silsesquioxanate ligand. DFT calculations were performed to analyse the molecular structure and NMR properties of the new platinum complex.
Keywords
Silsesquioxane , DFT calculation , Metallasilsesquioxane , Dinuclear platinum complex
Journal title
Journal of Organometallic Chemistry
Serial Year
2010
Journal title
Journal of Organometallic Chemistry
Record number
1377167
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