• Title of article

    A facile stereoselective synthesis of (E)-1,2-disubstituted vinylstannanes via hydromagnesiation of alkylarylacetylenes

  • Author/Authors

    Mingzhong Cai، نويسنده , , Jun Xia، نويسنده , , Guiqin Chen، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2004
  • Pages
    4
  • From page
    2531
  • To page
    2534
  • Abstract
    Hydromagnesiation of alkylarylacetylenes 1 in diethyl ether gave (E)-α-arylvinyl Grignard reagents 2, which reacted with trialkylstannyl chlorides 3 in diethyl ether to afford stereoselectively (E)-1,2-disubstituted vinylstannanes 4 in high yields.
  • Keywords
    Stereoselective synthesis , Vinyl Grignard reagent , Hydromagnesiation , Vinylstannane , Alkylarylacetylene , TIN
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2004
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1377234