Title of article
Two gold–ruthenium clusters derived from Ru3(μ-H)3(μ3-CBr)(CO)9
Author/Authors
Michael I. Bruce، نويسنده , , Paul A. Humphrey، نويسنده , , Brian W. Skelton، نويسنده , , Allan H. White، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2004
Pages
4
From page
2558
To page
2561
Abstract
The reaction between AuMe(PPh3) and Ru3(μ-H)3(μ3-CBr)(CO)9 (1) affords the novel heptanuclear cluster Au4Ru3(μ3-CMe)(Br)(CO)9(PPh3)3 (2), containing an Au/Ru3/Au trigonal pyramidal cluster face-capped by two Au(PPh3) groups and a CMe ligand, together with Au2Ru3(μ-H)(μ3-CMe)(CO)9(PPh3)2 (3), formed by isolobal replacement of two of the three μ-H atoms in 1 by Au(PPh3) groups. The latter co-crystallises with the analogous μ3-CH complex, as also shown spectroscopically.
Keywords
Gold , Ruthenium , Cluster
Journal title
Journal of Organometallic Chemistry
Serial Year
2004
Journal title
Journal of Organometallic Chemistry
Record number
1377237
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