Title of article
Synthesis and structure of a boron cation supported by a β-diketiminate ligand
Author/Authors
Alan H. Cowley، نويسنده , , Zheng Lu، نويسنده , , Jamie N. Jones، نويسنده , , Jennifer A. Moore، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2004
Pages
3
From page
2562
To page
2564
Abstract
The salt [HC(CMe)2(NAr)2BPh][Al2Cl7] (3); Ar = 2,6-i-Pr2C6H3) has been synthesized via the in situ preparation of [HC(CMe)2(NAr)2BClPh], followed by treatment with AlCl3. X-ray analysis of 3 reveals that the BN2C3 ring of the boron cation is planar and DFT calculations indicate π-type interactions in the HOMO-6 and HOMO-7 orbitals.
Keywords
Boron , ?-Diketiminate , Cation , X-ray , DFT calculation
Journal title
Journal of Organometallic Chemistry
Serial Year
2004
Journal title
Journal of Organometallic Chemistry
Record number
1377240
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