Title of article
Synthesis and structure of 1-iodo-7-dioxonium-decahydro-closo-dodecaborate
Author/Authors
Andrey Semioshkin، نويسنده , , Vladimir Bregadze، نويسنده , , Ivan Godovikov، نويسنده , , Anna Ilinova، نويسنده , , Julia Laskova، نويسنده , , Zoya Starikova، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
3
From page
2760
To page
2762
Abstract
Reaction of [B12H11I]2− with 1,4-dioxane in presence of HBF4 resulted in 1-iodo-7-(tetramethylene-(3-oxa)-oxonium)-decahydro-closo-dodecaborate regioselectively with good yield. Its structure, especially 1,7-isomery, was definitely proved by NMR and XRD methods. This novel compound has two reactive centers, perspective either for nucleophlic cleavage of dioxonium ring and/or for substitution of iodine in various cross-coupling reactions.
Keywords
Closo-dodecaborate , Oxonium derivatives , X-ray structure , Iodo derivatives
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1377315
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