Title of article :
Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand
Author/Authors :
Safaa Ibn Ghazala، نويسنده , , Frédéric Paul، نويسنده , , Loïc Toupet، نويسنده , , Claude Lapinte، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
A new cationic complex [(η2-bipy)(η5-C5Me5)Fe(η1-dppe)][BPh4] featuring a pendant free diphenylphosphine arm has been isolated in good yield after reaction of 2,2′-bipyridine with the known chloro precursor complex (η2-dppe)(η5-C5Me5)FeCl in presence of NaBPh4. This complex which can be envisioned as a new redox-active building-block has been structurally characterized.
Keywords :
Piano-stool , Iron(II) complex , ?1-Diphosphine , 2 , 2?-Bipyridine , Redox-active
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
