Title of article :
Oxygen activation on metallic centers and oxidizing abilities of such oxygen
Author/Authors :
Elena A. Zaburdaeva، نويسنده , , Viktor A. Dodonov، نويسنده , , Larisa P. Stepovik، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
It was shown that metallcontaining peroxides such as XOOOBu-t [X = (t-BuO)2Al, (t-BuO)3Ti] generate molecular oxygen in the electron-excited singlet state (1O2). These ozonides and η2-peroxocomplex Ph3Bi(η2O2) demonstrate high oxidative activity towards some classes of organic substances under mild conditions (20 °C).
Keywords :
Hydrocarbons , Sulfides , Sulfones , Nitroxyl radicals , Metallcontaining peroxides , Electron-excited singlet oxygen , Oxidation
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
