Title of article
Complexes of titanium and zirconium based on [C5Me4CH2-(2-C5H4N)] ligand
Author/Authors
Dmitrii P. Krut’ko، نويسنده , , Roman S. Kirsanov، نويسنده , , Sergey A. Belov، نويسنده , , Maxim V. Borzov، نويسنده , , Andrei V. Churakov، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
7
From page
1465
To page
1471
Abstract
Half-sandwich [η5:η1-κN-C5Me4CH2-(2-C5H4N)]MCl3 (M = Ti (4), Zr (5)) and sandwich [η5-C5Me4CH2-(2-C5H4N)][η5-C5Me5]ZrCl2 (6) ring-peralkylated complexes have been prepared and characterized. Evidence of the intramolecular coordination of the side-chain pyridyl group both in 4 and 5 in solutions is provided by NMR spectroscopy data. Crystal structure of an adduct 5-py with one molecule of pyridine has been established by X-ray diffraction analysis.
Keywords
N ligands , Cyclopentadienyl ligands , Zirconium , Oxidative addition , Reduction , Titanium
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377647
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