• Title of article

    Synthesis and molecular structure of hexanuclear organotitanium ion complex: image

  • Author/Authors

    Xiu-Feng Hou، نويسنده , , Shu Liu، نويسنده , , Pengcheng Zhang، نويسنده , , Guo-Xin Jin، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2007
  • Pages
    5
  • From page
    1766
  • To page
    1770
  • Abstract
    The reaction of bis[(2-methoxyethyl)cyclopentadienyl] titanium dichloride with dilithium dithiolato carborane in THF give a novel hexanuclear organotitanium ion complex View the MathML source[Cp6′Ti6(μ3-O)8][C2B10H10(μ-S2)2C2B9H10]2 (Cp′ = C5H4CH2CH2OCH3) ([1][2]2) as yellow crystal blocks. The cation [1]2+ has an octahedral metallic skeleton of six titanium atoms with the tricoordinated oxygen (μ3-O) and the anion [2]− consists of two S2 bridged 7,8-dicarbaundecaborate cluster and 1,2-dicarba-closo-dodecaborate cluster.
  • Keywords
    Hexanuclear complex , Cluster , carborane , Titanium , structure
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2007
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1377682