Title of article
The insertion reactions of “crowned” indium(I) trifluoromethanesulfonate into carbon–chlorine bonds
Author/Authors
Benjamin F.T. Cooper، نويسنده , , Christopher G. Andrews، نويسنده , , Charles L.B. Macdonald، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
6
From page
2843
To page
2848
Abstract
Whereas the soluble reagent indium(I) trifluoromethanesulfonate, InOTf, does not appear to react rapidly with chlorinated solvents, the crown ether ligated compounds [In(18-crown-6)][OTf] and [In(dibenzo-18-crown-6)][OTf] react rapidly with CH2Cl2 and CHCl3 to produce the corresponding C–Cl insertion products. The structural features and the formation of the new indium-containing products are rationalized.
Keywords
Insertion chemistry , Crown ether chemistry , Chlorocarbon solvents , Indium , Main group , Oxidative addition , Redox chemistry , Low oxidation state
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377809
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