Title of article
Germylene complexes of tungsten pentacarbonyls W(CO)5double bond; length as m-dashGeCl2 and W(CO)5double bond; length as m-dashGedouble bond; length as m-dashW(CO)5: Electrochemical synthesis and quantum-chemical computations
Author/Authors
Yulia G. Budnikova، نويسنده , , Tatyana V. Gryaznova، نويسنده , , Oleg G. Sinyashin، نويسنده , , Sergey A. Katsyuba، نويسنده , , Tatyana P. Gryaznova، نويسنده , , Mikhail P. Egorov، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
6
From page
4067
To page
4072
Abstract
Convenient synthetic route to prepare the germylene complexes of tungsten pentacarbonyls, W(CO)5double bond; length as m-dashGeCl2 and W(CO)5double bond; length as m-dashGedouble bond; length as m-dashW(CO)5, electrochemically is developed. Combined quantum-chemical/IR spectroscopic approach is used for identification of the synthesized compounds. Good agreement between theoretical and experimental spectra can be regarded as one of the proofs of their supposed structures.
Keywords
Dichlorogermylene complex of tungsten pentacarbonyls , Germylenebis(tungsten pentacarbonyl) complex , Electrolysis , Vibrational frequencies , Combined quantum-chemical/IR spectroscopic approach , Cyclic voltammetry
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377957
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