Title of article
Suzuki coupling catalyzed by a homoleptic Pd(I)–Pd(I) solvento complex
Author/Authors
Xiaoyan Han، نويسنده , , Zhiqiang Weng، نويسنده , , T. S. Andy Hor، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
7
From page
5690
To page
5696
Abstract
The PdI–PdI bonded complex [Pd2(CH3CN)6][SbF6]2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined.
Keywords
Suzuki coupling , Palladium , Dinuclear , Homoleptic , Catalyst
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1378230
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