Title of article :
New stable germylenes, stannylenes, and related compounds: 6. Heteroleptic germanium(II) and tin(II) compounds [(SiMe3)2N-E14-OCH2CH2NMe2]n (E14 = Ge, n = 1; Sn, n = 2): synthesis and structure
Author/Authors :
Victor N. Khrustalev، نويسنده , , Ivan A. Portnyagin، نويسنده , , Nikolay N. Zemlyansky، نويسنده , , Irina V. Borisova، نويسنده , , Mikhail S. Nechaev، نويسنده , , Yuri A. Ustynyuk، نويسنده , , Mikhail Yu. Antipin، نويسنده , , Valery Lunin، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2005
Abstract :
New stable heteroleptic germanium(II) and tin(II) compounds [(SiMe3)2N-E14-OCH2CH2NMe2]n (E14 = Ge, n = 1 (1), Sn, n = 2 (2)) have been synthesized and their crystal structures have been determined by X-ray diffraction analysis. While compound 1 is monomer stabilized by intramolecular Ge ← N coordination, compound 2 is associated to dimer via intermolecular dative Sn ← O interactions.
Keywords :
?-Dimethylaminoethoxy-ligand , X-ray analysis , Tin(II) , Germanium(II)
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
