Title of article
Synthesis of a Lewis acid bearing cyclopentadienyl ligand and its tricarbonylmanganese(I) complex
Author/Authors
Rhett T. Watson، نويسنده , , Jillian Basinger، نويسنده , , Endy Y. Min، نويسنده , , Paul S. Wagenknecht، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
4
From page
2159
To page
2162
Abstract
The synthesis of a bimetallic compound comprising a Lewis acidic organochlorostannane and a transition metal carbonyl is reported. The target complex, [(CO)3Mn(η5-C5H4(CH2)3SnMe2Cl)], 2, is prepared in four steps. The final step involves an exchange reaction between [(CO)3Mn(η5-C5H4(CH2)3SnMe3)], 1, and SnMe2Cl2. Infrared spectroscopy demonstrates no interaction between the Lewis acid and lone pair on the carbonyl oxygen.
Keywords
Organostannanes , CO activation , Heterobimetallic complexes , Intramolecular Lewis acid base adduct , Cyclopentadienyl ligands
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378419
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