Title of article
Azetidines as ligands in the Pd(II) complexes series
Author/Authors
Laurent Keller، نويسنده , , Monica Vargas Sanchez، نويسنده , , Damien Prim، نويسنده , , François Couty، نويسنده , , Gwilherm Evano، نويسنده , , Jérôme Marrot، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
6
From page
2306
To page
2311
Abstract
The preparation of palladium (II) complexes having sterically congested azetidines as ligands is described. Diastereomerically pure α-alkylamino and α-alkylimino azetidines react with Na2PdCl4 to afford the corresponding bidendate Pd(II) complexes, whereas 2-cyano azetidines can be used to access bidendate Pd(II) complexes containing an amino-imidate moiety. Preliminary study of the catalytic activity of these new complexes in the Suzuki cross-coupling reaction is presented.
Keywords
Azetidine , palladium complex , Imine , Imidate , Diamine
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378438
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