Title of article :
Synthesis and characterization of phospha-palladacycles and their catalytic properties in the olefination of chloro- and bromoarenes
Author/Authors :
Guido D. Frey، نويسنده , , Claus-Peter Reisinger، نويسنده , , Eberhardt Herdtweck، نويسنده , , Wolfgang A. Herrmann، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2005
Abstract :
Acetylacetonates of phospha-palladacycles are new catalysts in the Heck coupling of aryl chlorides and bromides with styrene. Turnover numbers (TON) of much higher than 300,000 and product yields up to 99% are obtained.
Keywords :
CC-coupling , Catalysis , Palladacycles , chloroarenes , Palladium , Heck reaction
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
