Title of article :
Synthesis and structure of the chiral palladium–fullerene C60 and C70 complexes with enantiomeric ligand 2,2′,5,5′-tetramethyl-4,4′-bis(diphenylphosphino)-3,3′-bithiophene [(−)tetraMe-BITIOP]
Author/Authors :
Vasily V. Bashilov، نويسنده , , Feodor M. Dolgushin، نويسنده , , Pavel V. Petrovskii، نويسنده , , Viatcheslav I. Sokolov، نويسنده , , Mara Sada، نويسنده , , Tiziana Benincori، نويسنده , , Gianni Zotti، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2005
Abstract :
η2-Fullerene (C60 and C70) palladium optically active complexes with the axially chiral enantiomeric ligand of bithienyl series, [(−)tetraMe-BITIOP], have been synthesized and investigated by 31P–{1H} NMR, electronic spectroscopy, CD spectroscopy, cyclic voltammetry and by single crystal X-ray diffraction.
Keywords :
Palladium–fullerene complexes , axial chirality , Optical activity , (?)tetraMe-BITIOP , circular dichroism , Cyclic voltammetry , NMR electronic spectroscopy , X-ray structure
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
