Title of article
A stable (amino)(phosphino)carbene as bidentate ligand for palladium and nickel complexes: Synthesis, structure, and catalytic activity
Author/Authors
Emmanuelle Teuma، نويسنده , , Céline Lyon-Saunier، نويسنده , , Heinz Gornitzka، نويسنده , , Gérard Mignani، نويسنده , , Antoine Baceiredo، نويسنده , , Guy Bertrand، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
5
From page
5541
To page
5545
Abstract
Two original complexes featuring an (amino)(phosphino)carbene η2-bonded to the metal have been obtained in 60% and 80% yields, by addition of the corresponding stable carbene to PdCl2(cod) and NiCl2(PPh3)2, respectively. Both complexes have been fully characterized including X-ray diffraction studies. The catalytic activity of the palladium complex has been evaluated for aryl amination reactions.
Keywords
carbenes , Bidentate ligands , palladium complexes , nickel complexes , Aryl amination reaction
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378894
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