Title of article :
3-Ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes
Author/Authors :
Elena I. Klimova، نويسنده , , Tatiana Klimova، نويسنده , , Leon V. Bakinovsky، نويسنده , , Marcos Martinez Garcia، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2006
Abstract :
Dehydrobromination of isomeric 3-bromo-1-ferrocenyl-2-methylcyclopropanes afforded 3-ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes. These undergo smooth opening of the three-membered ring to give 1- and 2-ferrocenylbuta-1,3-dienes and 1- and 2-methyl-1H-cyclopentaferrocenes; with 1,3-diphenylisobenzofuran they give the classical Diels–Alder adducts.
Keywords :
cyclopropene , Cyclopropane , Intramolecular transformations , Opening of the three-membered ring , Ferrocene
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry