Title of article
One-pot Pd-catalyzed hydrostannation/Stille reaction with acid chlorides as the electrophiles
Author/Authors
Kyoungsoo Lee، نويسنده , , William P. Gallagher، نويسنده , , Elli A. Toskey، نويسنده , , Wenzheng Chong، نويسنده , , Robert E. Maleczka Jr.، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
4
From page
1462
To page
1465
Abstract
A one-pot hydrostannation/Stille coupling sequence amenable to the employment of acid chloride electrophiles has been developed. In this protocol, palladium mediated alkyne hydrostannations using Me3SnF/PMHS as an in situ trimethyltin hydride source are followed by the addition of the acid chloride to afford a variety of α,β-unsaturated ketones in a single pot.
Keywords
Stille reaction , Acid chloride , Enone synthesis , Polymethylhydrosiloxane , TIN , hydrostannation
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379226
Link To Document