Title of article :
Desymmetrisation of bicyclo[4.4.0]decadienes: A planar-chiral complex proved to be most effective in an asymmetric Heck reaction
Author/Authors :
Matthias E.P. Lormann، نويسنده , , Martin Nieger، نويسنده , , Stefan Br?se، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2006
Abstract :
The synthesis and desymmetrisation of bicyclo[4.4.0]decadienes is described; the enantioselective Heck reaction using JOSIPHOS as a planar-chiral complex produces a tetracyclic system with three stereogenic centers in up to 84% enantiomeric purity.
Keywords :
JOSIPHOS , Desymmetrisation , Heck reaction
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
