Title of article
Diastereoselective addition of dimethyl phosphite to 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene-2-carboxaldehyde
Author/Authors
Damian Plazuk، نويسنده , , Janusz Zakrzewski، نويسنده , , Agnieszka Rybarczyk-Pirek، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
5
From page
3098
To page
3102
Abstract
Addition of dimethyl phosphite to racemic 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene-2-carboxaldehyde gives almost exclusively one diastereomer of the corresponding α-hydroxyphosphonate (d.r. ⩾96:4). Its absolute configuration (S, Rp)–(R, Sp) was established by X-ray diffraction.
Keywords
1 , 1?-diphosphaferrocene , ?-Hydroxyphosphonate , diastereoselective addition , Dimethyl phosphite , X-ray structure
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379429
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