Title of article
A oxygen-dependent reductive dechlorination of chloroform by (Bisdiphenylphosphinomethane)cobalthexacarbonyl Co2(CO)6(dppm)
Author/Authors
Meritxell Casadesus، نويسنده , , Michael P. Coogan، نويسنده , , Sarah Oakley، نويسنده , , Elenna Davies، نويسنده , , Li-Ling Ooi، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
3
From page
3715
To page
3717
Abstract
The reaction of Co2(μ-dppm)(CO)6 with aerated chloroform affords [Co{Ph2P(O)CH2P(O)Ph2}3][CoCl4] in low yield, and this reaction is demonstrated to be prevented under anaerobic conditions representing an unusual example of a reductive dechlorination which only takes place in the presence of oxygen.
Keywords
Dehalogenation , Cobalt carbonyl , Dicobalthexacarbonyl , Dechlorination , phosphines
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379512
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