Title of article
Synthesis of 2-methylidene-1-silacyclohexanes from 2,6-dibromohex-1-ene and polyhalosilanes
Author/Authors
Silvia D?ez-Gonz?lez، نويسنده , , Luis Blanco، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
9
From page
5531
To page
5539
Abstract
Various 2-methylidene-1-silacyclohexanes were prepared by straightforward syntheses from readily available polychloro- or polyfluorosilanes, magnesium and 2,6-dibromohex-1-ene using Barbier-type conditions or a previously synthesized Grignard reagent. Good yields were obtained considering the low stability of the products in the reaction conditions.
Keywords
vinylsilane , Fluorosilane , Organodimetallic reagent , Cyclization , Barbier-type conditions
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379680
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