Title of article :
Regioselective Oxidation of Steroids by a Manganese Porphyrin Carrying Metal Coordinating Groups
Author/Authors :
Belvedere، نويسنده , , Sandro and Breslow، نويسنده , , Ronald، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
A manganese porphyrin having four 2,2′-bipyridyl groups on its meso positions was synthesized. In the presence of Cu2+ ions it catalyzes the regioselective oxidation of steroid substrates carrying auxiliary metal coordinating groups.
Keywords :
steroid oxidation , Metal Coordination , cytochrome P450 , enzyme mimics.
Journal title :
Bioorganic Chemistry: an International Journal
Journal title :
Bioorganic Chemistry: an International Journal
