Association-induced polymer bridging by poly(ethylene oxide)–cofactor flocculation systems

Poly(ethylene oxide) (PEO) is used in papermaking, water purification and mineral flotation as a flocculating agent. Despite the fact that PEO does not adsorb on cellulose and bleached lignin, and only poorly on calcium carbonate, it can nevertheless be used to deposit colloidal pigments on pulp fibers. PEO by itself is inefficient, but it can be made to work in combination with another compound, usually referred to as a cofactor or an enhancer. The cofactor associates with PEO and the association complex acts as an efficient bridging agent. There are two classes of cofactor: those who cause PEO to cluster and those that do not. In general PEO association-clusters are more efficient flocculating agents than non-clustered PEO. The PEO dissolution procedure has an important effect on the PEO flocculation efficiency. Before reaching thermodynamic equilibrium, PEO is in an entangled state. Cofactors that cluster PEO are likely to maintain PEO in an entangled state and, like the association-clusters, these entanglements are more efficient flocculation agents than well-dispersed PEO. Salt also affects the PEO–cofactor association. For most cofactors, salt is needed to induce the association. Calcium ions can act as bridging agents between association complexes, especially those containing carboxyl groups, thus promoting the formation of association-clusters.