Elastic–plastic behavior of non-woven fibrous mats

Electrospinning is a novel method for creating non-woven polymer mats that have high surface area and high porosity. These attributes make them ideal candidates for multifunctional composites. Understanding the mechanical properties as a function of fiber properties and mat microstructure can aid in designing these composites. Further, a constitutive model which captures the membrane stress–strain behavior as a function of fiber properties and the geometry of the fibrous network would be a powerful design tool. Here, mats electrospun from amorphous polyamide are used as a model system. The elastic–plastic behavior of single fibers are obtained in tensile tests. Uniaxial monotonic and cyclic tensile tests are conducted on non-woven mats. The mat exhibits elastic–plastic stress–strain behavior. The transverse strain behavior provides important complementary data, showing a negligible initial Poissonʹs ratio followed by a transverse:axial strain ratio greater than −1:1 after an axial strain of 0.02. A triangulated framework has been developed to emulate the fibrous network structure of the mat. The micromechanically based model incorporates the elastic–plastic behavior of single fibers into a macroscopic membrane model of the mat. This representative volume element based model is shown to capture the uniaxial elastic–plastic response of the mat under monotonic and cyclic loading. The initial modulus and yield stress of the mat are governed by the fiber properties, the network geometry, and the network density. The transverse strain behavior is linked to discrete deformation mechanisms of the fibrous mat structure including fiber alignment, fiber bending, and network consolidation. The model is further validated in comparison to experiments under different constrained axial loading conditions and found to capture the constraint effect on stiffness, yield, post-yield hardening, and post-yield transverse strain behavior. Due to the direct connection between microstructure and macroscopic behavior, this model should be extendable to other electrospun systems and other two dimensional random fibrous networks.