Interaction potentials, structural ordering and effective charges in dispersions of charged colloidal particles

As colloidal dispersions of charged particles exhibit a wide variety of commercial, technological and scientific applications, a considerable theoretical effort has been devoted to finding an effective interaction potential from primitive models. The forces derived from this potential should justify the spatial ordering experimentally observed under certain conditions. This paper reviews the advances in these theoretical studies as well as some experiments (based on the mentioned order) that try to corroborate them. Special attention has been paid to the Derjaguin–Landau–Verwey–Overbeek (DLVO) potential. Nowadays, many of these theoretical investigations suggest that it could be applied if some of its parameters are renormalized. Nevertheless, to achieve a renormalization procedure in a strict way (from a primitive model) is a difficult task as a result of the size and charge asymmetries between small ions and macroions. Thus, several procedures for computing renormalized charges in a simple way have been developed. However, the notion of effective charge has also been widely used (as a adjustable parameter) in order to justify results found for several kinds of colloids (like solid particle dispersions or micellar systems) by means of quite different experimental techniques. Renormalization (as well as ion condensation) approaches, experiments and the controversial relationship between theoretical and phenomenological effective charges are also reviewed in this work.