Title of article :
Average structural analysis of the extractable material of young soot gathered in an ethylene inverse diffusion flame
Author/Authors :
Santamarيa، نويسنده , , Alexander and Mondragَn، نويسنده , , Fanor and Quiٌَnez، نويسنده , , Wiston and Eddings، نويسنده , , Eric G. and Sarofim، نويسنده , , Adel F.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
Conventional analytical methods such as 1H NMR, vapor pressure osmometry (VPO) and elemental analysis were used to characterize the soot precursor material represented by the chloroform extractable fractions of the young soot gathered at different heights of an ethylene inverse diffusion flame in terms of average structural parameters. The results indicate that the soot soluble fraction obtained at a 6 mm height has a relatively large molecular weight and has long aliphatic chains which later disappear with an increase in height above the burner base, especially in the region where the temperature is high (1200 K). This behavior is also accompanied by an increase in the aromaticity (fa) of the samples.
Keywords :
Soot , Nuclear magnetic resonance , Average structural parameters