• Title of article

    Estimation of heteroscedastic measurement noise variances

  • Author/Authors

    de Brauwere، نويسنده , , Anouk and Pintelon، نويسنده , , Rik and De Ridder، نويسنده , , Fjo and Schoukens، نويسنده , , Johan and Baeyens، نويسنده , , Willy، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2007
  • Pages
    9
  • From page
    130
  • To page
    138
  • Abstract
    For any quantitative data interpretation it is crucial to have information about the noise variances. Unfortunately, this information is often unavailable a priori. We propose a procedure to estimate the noise variances starting from the residuals. The method takes two difficulties into account. (i) The noise can be heteroscedastic (not constant over the measurement domain). This implies that one number is not enough anymore to characterise the total noise variance structure. (ii) The initial model used to generate the residuals may be imperfect. As a consequence, the residuals contain more than only stochastic information. The outcome of our procedure is an estimate of the noise variances which depends on the sample number, but is independent of the postulated model. A by-product of the procedure is information about the distribution of the degrees of freedom over the measurement domain. Indeed, as a consequence of the heteroscedastic noise, the model parameters will be fitted more to those data with low uncertainty and most of the degrees of freedom are lost at these locations.
  • Keywords
    Heteroscedasticity , Residuals , Noise variance estimation
  • Journal title
    Chemometrics and Intelligent Laboratory Systems
  • Serial Year
    2007
  • Journal title
    Chemometrics and Intelligent Laboratory Systems
  • Record number

    1461863