Deep hydrodesulphurization and hydrogenation of diesel fuels on alumina-supported and bulk molybdenum carbide catalysts

Deep hydrodesulphurization (HDS) of diesel fuels has been carried out on P (Ni)-promoted or non-promoted Mo2C-supported γ-Al2O3 and bulk Mo2C under standard industrial conditions (613 K, 3 MPa). The effect of the promoter was investigated for different feedstocks on HDS and hydrogenation (HYD) with very low levels of sulfur. The temperature effect was also followed. The HDS conversion indicates that phosphorus promoted alumina supported carbide catalysts are as active as a commercial Co–Mo/Al2O3 catalyst for low levels of sulfur in the feed. Furthermore, the refractory compounds such as 4,6-dimethyldibenzothiophene are only transformed on molybdenum carbide catalyst in industrial conditions for hydrotreated gas oils. With gas oils with less than 50 wt ppm in sulfur, phosphorus promoted molybdenum carbide catalysts become more active than commercial catalysts for the HYD of the aromatic compounds and the HDS or the HDN of the feedstock.