Influence of low-density polyethylene addition on coking pressure

Different amounts of low-density polyethylene (LDPE) were added to a bituminous coal used to produce metallurgical coke. The effect of the plastic waste on the carbonization process and more exactly, on the coking pressure were investigated. A movable wall oven at semi-pilot scale was used for measuring coking pressure generated. It was found that coking pressure increases for low LDPE addition levels (1–3 wt.%); however higher amounts of LDPE reduce coking pressure. To explain this behavior different blends of the coal and the residue were pyrolysed at three different temperatures (450, 500 and 600 °C) in a Gray-King apparatus. The results show that LDPE causes a modification in the pyrolysis process and also influences the swelling process of the plastic stage. crease of the coking pressure at low LDPE addition rates is associated with a less permeable coal plastic layer, which prevents the removal of the decomposition products and causes their retention in the semicoke matrix, evolving them in the post-plastic stage. Coking pressure decrease at high LDPE addition rates can be due to the charge shrinkage and the better permeability to the migration of oil components, which suggest a lower interaction between the coal and the LDPE. A delay in the degradation of LDPE is confirmed by the data provided by DRIFT and SEM.