Author/Authors :
Salmani، Mohammad Hossein نويسنده 1Department of Environmental Health Engineering, Faculty of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran , , Ehrampoush، Mohammad Hassan نويسنده Department of Environmental Health Engineering, School of Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran , , Aboueian -Jahromi، Mohaddeseh نويسنده Department of Environmental Health Engineering, Faculty of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran , , Askarishahi، Mohsen نويسنده Department of Environmental Health Engineering, Faculty of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran ,
Abstract :
The impact of effective parameters such as iron oxide nanoparticles dosage, contact time and solution pH was
optimized for removal of Ag(I) and Ni(II) in the nuclear cooling system and the best conditions were compared.
Nearly complete removal (97%) of Ni(II) and Ag(I) were obtained at adsorbent dosage of 40 and 20 g/L,
respectively. Experiments showed that 4 hours was a good choice as optimum contact time for two ions removal.
The effective parameter was pH, so that maximum removal efficiency was obtained for Ag(I) in acidic pH=3 and for
Ni(II) in basic pH=10. It seems that removal of Ag(I) was controlled by adsorption-reduction mechanism, but Ni(II)
could place only adsorption. Langmuir and Freundlich model was more suitable for nickel and silver removal by
this adsorbent, respectively. Ag(I) and Ni(II) removal efficiency trend by this adsorbent is similar at periods but
different in the concentrations, pHs and equilibrium model. The obtained results were very promising, as both Ag(I)
and Ni(II) were effectively removed from synthetic wastewater and there was a possibility to remove Ag(I) very fast.
Hence, the idea of using nanoparticles for application of metal ions removal from wastewaters seems to be very
efficient and quite promising.