The dependence of equilibrium partition coefficient of cesium and iodine between sodium pool and the inert cover gas on the concentration in the pool

Equilibrium partition coefficients were experimentally measured for volatile fission products of cesium and iodine between liquid sodium pool and the inert cover gas. In the experiments, the “transpiration method” was utilized in which the saturation vapor of sodium with cesium and iodine vapor in an isothermal evaporation pot was transported by inert carrier gas and trapped by filters outside the pot. The objectives of the experiments are to:(a) the equilibrium partition coefficients of cesium and iodine at high temperature between 600 and 850 °C and, the dependence of the partition coefficients upon the concentration in the sodium pool. he results of previous work and this study, the following empirical equations between the partition coefficients of cesium and iodine and the sodium pool temperature could be obtained: log     K d ( Cs ) = 2173 T − 1.0487   ( from     450   to   850   ° C ) , log     K d ( I ) = − 215 T − 0.271   ( from     450   to   850   ° C ) . equations are consistent with Castlemanʹs theoretical equations. The partition coefficients of cesium measured at five different points of mole concentration in the pool were almost consistent with the theoretical values and decreased with the increase in the concentration. On the other hand, the measured partition coefficients of iodine increased with the increase in the concentration in the pool and this tendency was incompatible with the theoretical consideration. This discrepancy could be explained considering the formation of dimmer of NaI (Na2I2) in the cover gas.