Title of article
A simple route to hexamethylguanidinium fluoride
Author/Authors
Kolomeitsev، نويسنده , , A.A and Bissky، نويسنده , , G and Kirsch، نويسنده , , P and Rِschenthaler، نويسنده , , G.-V، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
159
To page
161
Abstract
Tetramethylchloroformamidinium chloride reacts with 2 mol equivalents of tetramethylammonium fluoride to give bis(dimethylamino)difluoromethane (1). The treating of 1 with dimethylaminotrimethylsilane in acetonitrile yields quantitatively hexamethylguanidinium fluoride (2). Reaction of 2 with (trifluoromethyl)trimethylsilane provides an easy access to 1,1,1-trifluoro-2,2,2-tris(dimethylamino)ethane (4).
Keywords
‘Naked’ fluoride ion , Hexamethylguanidinium fluoride
Journal title
Journal of Fluorine Chemistry
Serial Year
2000
Journal title
Journal of Fluorine Chemistry
Record number
1602893
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