Title of article
Halogens halt aromatic group migration in Baeyer–Villiger oxidation
Author/Authors
Adejare، نويسنده , , Adeboye and Shen، نويسنده , , Jun and Ogunbadeniyi، نويسنده , , Alaba M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
107
To page
109
Abstract
Oxidation of a dihalogenated benzaldehyde under Baeyer–Villiger conditions led to the aromatic carboxylic acid as opposed to the desired phenol. Fluorine was located at the para-position of the benzaldehyde, halting migration of the aryl group and thus resulting in the carboxylic acid product.
Keywords
Fluorobenzaldehyde , Fluorocarboxylic acid , Baeyer–Villiger oxidation mechanism
Journal title
Journal of Fluorine Chemistry
Serial Year
2000
Journal title
Journal of Fluorine Chemistry
Record number
1602956
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