• Title of article

    Pyrolysis of benzenediazonium bis(trifluoromethanesulfonyl)methide

  • Author/Authors

    Ishihara، نويسنده , , Kazuaki and Hasegawa، نويسنده , , Aiko and Yamamoto، نويسنده , , Hisashi، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    3
  • From page
    139
  • To page
    141
  • Abstract
    The pyrolysis of benzenediazonium bis(trifluoromethanesulfonyl)methide in the absence of solvents did not give the carbon arylation product, PhCH(SO2CF3)2, but the oxygen phenylation product, PhO(CF3)S(O)CHSO2CF3, in good yield. In contrast, the pyrolysis of the same compound in acetonitrile gave the acetonitrile-inserted compound, PhNH(Me)CC(SO2CF3)2, quantitatively.
  • Keywords
    Benzenediazonium bis(trifluoromethanesulfonyl)methide , Acetonitrile , Pyrolysis
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1603011