Title of article
Nucleophilic displacements of 2-perfluoroalkyl-1-iodoethanes: improved synthesis of fluorine-containing malonic esters
Author/Authors
Trabelsi، نويسنده , , F. and Szِnyi، نويسنده , , F and Geribaldi، نويسنده , , S، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
5
From page
177
To page
181
Abstract
The replacement of iodide in 2-perfluoroalkyl-1-iodoethanes by anions derived from dialkyl malonate affords α-(2-perfluoroalkyl)ethyl malonic esters in high yields with negligible elimination and dialkylation, using bases such as K2CO3 or NaH in THF. The physical properties of the products are described.
Keywords
2-Perfluoroalkyl-1-iodoethane , Dialkyl-?-(2-perfluoroalkylethyl)malonic esters , Dialkyl-? , ?-di(2-perfluoroalkylethyl)malonic esters , Dialkyl malonate
Journal title
Journal of Fluorine Chemistry
Serial Year
2001
Journal title
Journal of Fluorine Chemistry
Record number
1603054
Link To Document