Title of article
Synthesis of novel chiral quaternary phosphonium fluorides: reagents for simple asymmetric nucleophilic fluorination reactions
Author/Authors
Beaumont، نويسنده , , Andrew J. and Kiely، نويسنده , , Christopher and Denise Rooney، نويسنده , , A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
47
To page
50
Abstract
The novel chiral quaternary salt (RP)-benzylmenthylmethylphenylphosphonium fluoride was synthesised. The compound was used in the asymmetric nucleophilic fluorination of 2-bromopropiophenone to give 2-fluoropropiophenone in a 35% yield with [α]D20=+1.94°.
Keywords
asymmetric , nucleophilic , fluorination , Chiral , Phosphonium , fluoride
Journal title
Journal of Fluorine Chemistry
Serial Year
2001
Journal title
Journal of Fluorine Chemistry
Record number
1603098
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