Title of article :
Synthesis and crystal structure of guanidinium tetrafluoro(trans-)dipyridinechromate(III), [CrF4(C5H5N)2]−·CN3H6+
Author/Authors :
Thoma، نويسنده , , Steven G. and Bonhomme، نويسنده , , François and Nyman، نويسنده , , May and Rodriguez، نويسنده , , Mark A. and Nenoff، نويسنده , , Tina M.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
A new chromium coordination compound, guanidinium tetrafluoro(trans-)dipyridinechromate(III), has been synthesized in one step under mild solvothermal conditions. [CrF4(C5H5N)2]−·[CN3H6]+crystallizes in the monoclinic space group P21/n, with a=8.6054(8) Å, b=13.3529(12) Å, c=13.2952(12) Å, and β=100.62(2)°. The structure consists of discrete guanidinium cations, CN3H6+, and tetrafluorodipyridinechromate anions, CrF4(C5H5N)2−.
Keywords :
hydrogen bonded network , Coordination compound , Synthesis , Chromium , Guanidinium , Fluorochromate , Fluoroamine , crystal structure
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
