• Title of article

    Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

  • Author/Authors

    Sekiya، نويسنده , , Akira and Quan، نويسنده , , Heng-dao and Tamura، نويسنده , , Masanori and Gao، نويسنده , , Ren-Xiao and Murata، نويسنده , , Junji، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    145
  • To page
    148
  • Abstract
    Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.
  • Keywords
    Porous aluminum fluoride , 2-trifluoro-2-methoxyethane , 1 , 1 , 2-chloro-1 , 1 , 2-tetrafluoro-2-methoxyethane , Methyl chlorodifluoroacetate , 2 , 2-dichloro-1
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1603339