Title of article
The behaviour of chlorofluoroethanes on β-aluminium(III) fluoride: a [36Cl] radiotracer study
Author/Authors
Bozorgzadeh، نويسنده , , Hamid and Kemnitz، نويسنده , , Erhard and Nickkho-Amiry، نويسنده , , Mahmood and Skapin، نويسنده , , Toma? and Tate، نويسنده , , Graeme D and Winfield، نويسنده , , John M، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
8
From page
225
To page
232
Abstract
A [36Cl] radiotracer study of the behaviour of 1,1,2-trichlorotrifluoroethane on β-aluminium(III) fluoride at elevated temperature indicates that the isomerisation of CCl2FCClF2 to CCl3CF3 occurs by an intramolecular process. Isomerisation is followed by dismutation of CCl3CF3 to give CCl2FCF3 and CCl3CClF2. In neither reaction, surface Al–Cl groups are formed. The compound CCl3CClF2 undergoes further reaction, readily, apparently also via dismutation processes.
Keywords
chlorine-36 , Chlorofluoroethane , Dismutation
Journal title
Journal of Fluorine Chemistry
Serial Year
2001
Journal title
Journal of Fluorine Chemistry
Record number
1603362
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